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Aldrich

Dess-Martin periodinane

274623 -

97%

DOWNLOAD MSDS (PDF)

Synonym: 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one

Properties

Related CategoriesHypervalent Iodine, Oxidation, Synthetic Reagents
assay97%
mp130-133 °C(lit.)

Description

Application

Oxidizing agent for 1° and 2° alcohols to aldehydes and ketones.1,2

Used for the oxidation of hydroxychlorins to chlorin-α-diones and tetraones.

Packaging

1, 5, 25, 50 g in glass btl

Price and Availability

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anhydrous, ≥99.9%


Documents

Certificate of Analysis

Certificate of Origin

ChemFiles Vol 1 No 5 (1 MB )
Structure Search
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Safety Information

SymbolGHS03GHS07  GHS03, GHS07
Signal wordWarning
Hazard statementsH272-H302-H312-H315-H319-H332-H335
Precautionary statementsP220-P261-P280-P305 + P351 + P338
Supplemental Hazard StatementsRisk of explosion if heated under confinement.
Personal Protective Equipmentdust mask type N95 (US), Eyeshields, Gloves
Hazard CodesXn
Risk Statements20/21/22-36/37/38
Safety Statements26-36
WGK Germany3
Technical information & documentation associated with this product is available in the Safety & Documentation tab.

References

1. J. Org. Chem. 48, 4155, (1983)

2. Adv. Syn. Catalysis 346, 111-124, (2004)

J. Porphyrins Phthalocyanines 9, 444, (2005)

Merck 14,2933

Fieser 12,378 / Fieser 15,252 / Fieser 16,271 / Fieser 17,271

Corp MSDS 1 (1), 1033:B / RegBook 1 (2), 1939:N


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